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Between episode 1 and episode 56, there would be a new villain or villains each week for the Magical Princess to fight.

Some of these villains would return in later episodes, while others would never appear again.

Please note that some villains are exclusive to the anime and do not have a manga counterpart.

Villains

Akazukin Chacha Villains of the Week
Evil Mirror
Episode 1
Evil Mirror
Villain:
Evil Mirror
Dark Rascal Sensei
Episode 2
Dark Rascal Sensei
Villain:
Evil Starfish
Episode 3
Evil Starfish
Villain:
{{{Villain}}}
Dokuga
Episode 4
Dokuga
Villain:
{{{Villain}}}
Que-chan The Vampire
Episode 5
Que-chan The Vampire

Villain:
{{{Villain}}}
Kan-kan & Lan-lan
Episode 6 & 38
Kan-kan & Lan-lan, The Twin Witches
Villain:
{{{Villain}}}
Uma-X Mole Kaiju
Episode 7
Uma-X Mole Kaiju

Villain:
{{{Villain}}}
Cream The Pastry Witch
Episode 8
Cream The Pastry Witch

Villain:
{{{Villain}}}
Nyandaber Z
Episode 9
Professor Mikeneko's Nyandaber Z
Villain:
{{{Villain}}}
Strengthend Que-chan
Episode 10
Strengthened Que-chan

Villain:
{{{Villain}}}
Battle Sushimaster
Episode 11
Battle Sushimaster

Villain:
{{{Villain}}}
Kotetsu The Cursed Blade
Episode 12
Kotetsu, The Cursed Blade

Villain:
{{{Villain}}}
Foxy Kaiju
Episode 13
Foxy Kaiju
Villain:
{{{Villain}}}
Professor Hawking
Episode 14
Professor Hawking
Villain:
{{{Villain}}}
Franken-chan Kaiju
Episode 15
Franken-chan Kaiju
Villain:
{{{Villain}}}
3-Eyed King Jellyfish
Episode 16
3-Eyed King Jellyfish
Villain:
{{{Villain}}}
Nyandaber ZZ
Episode 17
Nyandaber ZZ
Villain:
{{{Villain}}}
Cupie Fell
Episode 18
Cupie Fell
Villain:
{{{Villain}}}
Battle Barber
Episode 19
Battle Barber
Villain:
{{{Villain}}}
Nezumi Kid
Episode 20
Nezumi Kid
Villain:
{{{Villain}}}
Giant Rat Robot
Episode 21
Giant Rat Robot
Villain:
{{{Villain}}}
Beppu
Episode 21
Beppu
Villain:
{{{Villain}}}
Giant Beppu
Episode 21
Giant Beppu
Villain:
{{{Villain}}}
Oroshi The Hydra
Episode 22
Oroshi, The Hydra
Villain:
{{{Villain}}}
Unskya The Iron Ball Golem
Episode 23
Unskya, The Iron Ball Golem
Villain:
{{{Villain}}}
Haideyans Tyranosaurus Form
Episode 24
Haideyans Tyranosaurus Form
Villain:
{{{Villain}}}
Lobster-Crab Hybrid Kaiju
Episode 25
Haideyans & Yordas's Lobster-Crab Hybrid Kaiju
Villain:
{{{Villain}}}
Access
Episode 25-33
Access, Shiine-chan's Father
Villain:
{{{Villain}}}
Phoenix Butterfly
Episode 27
Phoenix Butterfly

Villain:
{{{Villain}}}
Bird The Mind Reading Frog
Episode 28
Bird, The Mind Reading Frog
Villain:
{{{Villain}}}
Evil Tree Demon
Episode 29
Evil Tree Demon

Villain:
{{{Villain}}}
Gandar
Episode 30
Gandar

Villain:
{{{Villain}}}
Cursed Armor Knight
Episode 32
Cursed Armor Knight
Villain:
{{{Villain}}}
Spidia
Episode 34
Spidia
Villain:
{{{Villain}}}
Great Nyandaber
Episode 35
Great Nyandaber
Villain:
{{{Villain}}}
Miraado
Episode 36
Miraado
Villain:
{{{Villain}}}
Makkin
Episode 37
Makkin
Villain:
{{{Villain}}}
King Panda
Episode 38
King Panda
Villain:
{{{Villain}}}
Otto The Kappa Kaiju
Episode 39
Otto, The Kappa Kaiju
Villain:
{{{Villain}}}
Ka Zandan
Episode 41
Ka Zandan
Villain:
{{{Villain}}}
Super Bariki Massuru
Episode 42
Super Bariki Massuru

Villain:
{{{Villain}}}
Kyotoora
Episode 43
Kyotoora

Villain:
{{{Villain}}}
Harpy
Episode 44
Harpy

Villain:
{{{Villain}}}
Modoking
Episode 45
Modoking, The Shapeshifting Blob
Villain:
{{{Villain}}}
Dark Princess Chacha
Episode 45
Dark Magical Princess
Villain:
{{{Villain}}}
Gekkou
Episode 46
Gekkou
Villain:
{{{Villain}}}
Garrok
Episode 47
Garrok
Villain:
{{{Villain}}}
Tanuki Bunbuku Teapot
Episode 48
Tanuki Bunbuku Teapot
Villain:
{{{Villain}}}
Daimao
Episode 50
Daimao, The Great Evil Lord
Villain:
{{{Villain}}}
Sponge Giant
Episode 52
Sponge Giant

Villain:
{{{Villain}}}
Hurricane Ken
Episode 53
Hurricane Ken

Villain:
{{{Villain}}}
Buki
Episode 54
Buki, The Robotic Magic Instructor
Villain:
{{{Villain}}}
Soprano & Baritone
Episode 55 & 56
Soprano & Baritone
Villain:
{{{Villain}}}
  • This marks the end of all villains defeated by Magical Princess
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